Search results

Page title matches

Page text matches

• Bailar twist
  [[Category:Coordination chemistry]]
  1 KB (152 words) - 20:18, 21 September 2010
• Ray-Dutt twist
  [[Category:Coordination chemistry]]
  1 KB (159 words) - 20:18, 21 September 2010
• Oxidative addition
  In '''oxidative addition''', a metal complex with vacant coordination sites and a relatively low [[oxidation state]] is oxidized by the [[Inserti ...the two groups (X and Y) should be adjacent to each other in the metal's [[coordination sphere]]. Reductive elimination is the key product releasing step of severa
  3 KB (457 words) - 20:18, 21 September 2010
• Sn1CB mechanism
  ...e base) mechanism''' describes the pathway by which many metal [[amine]] [[Coordination chemistry|complexes]] undergo substitution, that is [[ligand exchange]]. Ty [[Category:Coordination chemistry]]
  1 KB (221 words) - 20:18, 21 September 2010
• Jahn–Teller effect
  The expected effects for octahedral coordination are given in the following table: [[Category:Coordination chemistry]]
  8 KB (1,101 words) - 20:18, 21 September 2010
• Pincer ligand
  ...er ligand, although in some cases one arm is hemi-labile and an additional coordination site is generated transiently. Early examples of pincer ligands (not calle Many tridentate ligands types occupy three contiguous, coplanar coordination sites. The most famous such ligand is [[terpyridine]] (“terpy”). Terpy
  5 KB (747 words) - 20:18, 21 September 2010
• Reductive elimination
  [[Category:Coordination chemistry]]
  190 bytes (17 words) - 20:18, 21 September 2010
• Nephelauxetic effect
  [[Category:Coordination chemistry]]
  3 KB (429 words) - 20:18, 21 September 2010
• Bite angle
  ...CO complex and during the hydride migration step that follows. During the coordination of the alkene to the intermediate complex, the effect of bite angle on the [[Category:Coordination chemistry]]
  12 KB (1,706 words) - 20:18, 21 September 2010
• Ligand
  ...also: [[functional group]]) that binds to a central metal-atom to form a [[coordination complex]]. The bonding between metal and ligand generally involves formal ...xplain many of the previously inexplicable isomers. He resolved the first coordination complex called [[hexol]] into optical isomers, overthrowing the theory that
  25 KB (3,607 words) - 20:18, 21 September 2010
• Trans-spanning ligand
  ...chains to link the donor functionalities, but such ligands often lead to [[coordination polymer]]s. [[Category:Coordination chemistry]]
  3 KB (366 words) - 20:18, 21 September 2010
• Denticity
  .../D01594.html ''denticity'']</ref><ref>von Zelewsky, A. "Stereochemistry of Coordination Compounds" John Wiley: Chichester, 1995. ISBN 047195599.</ref> In many cas ...are particularly useful for binding lanthanide ions, which typically have coordination numbers greater than 6.
  4 KB (572 words) - 20:18, 21 September 2010
• Tris(2-aminoethyl)amine
  | Coordination = <!-- edge-shared bioctahedron --> ...Abbreviated "tren," it is the archetypal tripodal ligand of interest in [[coordination chemistry]].
  4 KB (584 words) - 20:18, 21 September 2010
• Ate complex
  ...>. (Note that in this definition the meaning of valence is equivalent to [[coordination number]]) Often in [[chemical nomenclature]] the phrase ''ate'' is [[suffix [[Category:Coordination chemistry]]
  2 KB (214 words) - 20:18, 21 September 2010
• Spin states (d electrons)
  ...igurations can be understood through the two major models used to describe coordination complexes; [[ligand field theory]], which is an application of [[molecular ...l|''d''-orbitals]] plays an important role in the electron spin state of a coordination complex. There are three factors that affect the Δ: the period of the meta
  8 KB (1,140 words) - 20:18, 21 September 2010
• Associative substitution
  ...gand]]s. The terminology is typically applied to [[Coordination chemistry|coordination]] and [[Organometallic chemistry|organometallic]] complexes, but resembles ...tically held nucleophile can exchange positions with a ligand in the first coordination sphere, resulting in net substitution. An illustrative process comes from t
  6 KB (838 words) - 20:18, 21 September 2010
• Dissociative substitution
  ...ge [[ligand]]s. The term is typically applied to [[Coordination chemistry|coordination]] and [[Organometallic chemistry|organometallic]] complexes, but resembles ...[[nucleophile]] has no influence on this rate. An intermediate of reduced coordination number can be detected. Complexes that undergo dissociative substitution a
  4 KB (630 words) - 20:18, 21 September 2010
• LIESST
  [[Category:Coordination chemistry]]
  2 KB (315 words) - 20:18, 21 September 2010
• Sterically induced reduction
  [[Category:Coordination chemistry]]
  5 KB (727 words) - 20:18, 21 September 2010
• Tetracoordinate
  '''Tetracoordinate''' in [[coordination chemistry]] generally refers to four [[ligand]]s or atomic attachments to a [[Category:Coordination chemistry]]
  531 bytes (61 words) - 20:18, 21 September 2010

View (previous 20 | next 20) (20 | 50 | 100 | 250 | 500)