Slag

For other uses, see Slag (disambiguation).

File:Slag2.jpg

A path through a slag heap in Clarkdale, Arizona, showing the striations from the rusting corrugated sheets retaining it.

File:The Manufacture of Iron -- Carting Away the Scoriae.jpg

The Manufacture of Iron -- Carting Away the Scoriæ (slag), an 1873 wood engraving

File:Slag runoff Republic Steel.jpg

Slag run-off from one of the open hearth furnaces of a steel mill, Republic Steel, Youngstown, Ohio. Slag is drawn off the furnace just before the molten steel is poured into ladles for ingotting.

Slag is a partially vitreous by-product of smelting ore to separate the metal fraction from the unwanted fraction. It can usually be considered to be a mixture of metal oxides and silicon dioxide. However, slags can contain metal sulfides (see also matte) and metal atoms in the elemental form. While slags are generally used as a waste removal mechanism in metal smelting, they can also serve other purposes, such as assisting in the temperature control of the smelting; and also minimizing any re-oxidation of the final liquid metal product before the molten metal is removed from the furnace and used to make solid metal.

Ore smelting

In nature, the ores of metals such as iron, copper, lead, aluminium, and other metals are found in impure states, often oxidized and mixed in with silicates of other metals. During smelting, when the ore is exposed to high temperatures, these impurities are separated from the molten metal and can be removed. The collection of compounds that is removed is the slag. In many smelting processes, oxides are introduced to control the slag chemistry, assisting in the removal of impurities and protecting the furnace refractory lining from excessive wear. In this case, the slag is termed synthetic. A good example is steelmaking slag: quicklime and magnesite are introduced for refractory protection, neutralising the alumina and silica separated from the metal, and assist in the removal of sulfur and phosphorus from the steel.

Ferrous and non-ferrous smelting processes produce different slags. The smelting of copper and lead in non-ferrous smelting, for instance, is designed to remove the iron and silica that often occurs with those ores, and separates them a an iron-silicate-based slags. Slag from steel mills in ferrous smelting, on the other hand, is designed to minimize iron loss and so mainly contains oxides of calcium, silicon, magnesium, and aluminium. Any sandy component or quartz component of the original ore automatically carries through the smelting process as silicon dioxide.

Ancient slag use

During the Bronze Age of the Mediterranean there were a vast number of differential metallurgical processes in use. A slag by-product of such workings was a colorful, glassy, vitreous material found on the surfaces of slag from ancient copper foundries. It was primarily blue or green and was formerly chipped away and melted down to make glassware products and jewelry. It was also ground into powder to add to glazes for use in ceramics. Some of the earliest such uses for the by-products of slag have been found in ancient Egypt.

Historically, the re-smelting of iron ore slag was common practice as improved smelting techniques permitted greater iron yields - in some case exceeding that which was originally achieved. This remains an option today, but the relatively small size of iron ore heaps often renders it financially un-viable. During the early 20th century, iron ore slag was also ground to a powder and used to make 'Agate Glass', also known as 'Slag Glass'.

Modern slag uses

Ground granulated slag is often used in concrete in combination with Portland cement as part of a blended cement. Ground granulated slag reacts with water to produce cementitious properties. Concrete containing ground granulated slag develops strength over a longer period, leading to reduced permeability and better durability. Since the unit volume of Portland cement is reduced, this concrete is less vulnerable to alkali-silica and sulfate attack.

When iron ore is heated in a blast furnace, the impurities or ‘slag’, which include large quantities of calcium and silica, become molten and are separated from the raw iron.

As the slag is channeled out of the furnace, thousands of gallons of water are poured over it. This rapid cooling, often from a temperature of around 2,600°C, is the start of the granulating process. This process causes several chemical reactions to take place within the material, and gives the slag its cementitious properties.

The water carries the slag in its slurry format to a large agitation tank, from where it is pumped along a piping system into a number of gravel based filter beds. The filter beds then retain the slag granules, while the water filters away and is returned to the system.

When the filtering process is complete, the remaining slag granules, which now give the appearance of coarse beach sand, can be scooped out of the filter bed and transferred to the grinding facility where they are ground into particles that are finer than Portland cement

This previously unwanted recycled product is used in the manufacture of high performance concretes, especially those used in the construction of bridges and coastal features, where its low permeability and greater resistance to chlorides and sulfates can help to reduce corrosive action and deterioration of the structure.

Basic slag

Basic slag is a byproduct of steelmaking by the basic version of the Bessemer process or the Linz-Donawitz process. It is largely limestone or dolomite which has absorbed phosphate from the iron ore being smelted. Because of the slowly-released phosphate content, as well as for its liming effect, it is valued as fertilizer in gardens and farms in steelmaking areas. According to the American Association of Plant Food Control Officials, basic slag must contain at least 12% total phosphoric acid (P₂O₅) or be labeled "low phosphate".

See also

• Cement
• Dross
• Fly ash
• Ground granulated blast furnace slag
• Matte (metallurgy)
• Pozzolan
• Slag heap

References

Bibliography

• Dimitrova, S.V. (1996). "Metal sorption on blast-furnace slag". Water Research. 30 (1): 228–232. doi:10.1016/0043-1354(95)00104-S. 

• Roy, D.M. (1982). "Hydration, structure, and properties of blast furnace slag cements, mortars, and concrete". ACI Journal Proceedings. 79 (6). 

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