Bromodifluoroacetyl chloride
From Self-sufficiency
| Bromodifluoroacetyl chloride | |
|---|---|
| File:Bromodifluoroacetylchloride.png | |
| 2-bromo-2,2-difluoro-ethanoyl chloride | |
| style="background: #F8EABA; text-align: center;" colspan="2" | Identifiers | |
| CAS number | 3832-48-2 |
| PubChem | 520892 |
| SMILES | Script error: No such module "collapsible list". |
| style="background: #F8EABA; text-align: center;" colspan="2" | Properties | |
| Molecular formula | C2BrClF2O |
| Molar mass | 193.37 g mol−1 |
| Appearance | liquid |
| Boiling point |
50°C |
| style="background: #F8EABA; text-align: center;" colspan="2" | Hazards | |
| MSDS | [1] |
| EU classification | Corrosive (C) |
| R-phrases | R34 |
| S-phrases | S36/37/39, S45 |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
| Infobox references | |
Bromodifluoroacetyl chloride is a chemical compound with the formula BrCF2COCl. It has been used as a starting material for the synthesis of (biologically active) α,α-difluoro-γ-lactams[1] and has been used in the synthesis of trifluoromethylated C-nucleosides.[2]
References
- ↑ Hideo Nagashima, Yoshimi Isono, and Sho-ichi Iwamatsu (2001). "Copper-Catalyzed Cyclization of N-Allylhalodifluoroacetamides: An Efficient Synthesis of α,α-difluoro-γ-lactams". J. Org. Chem. 66 (1): 315–319. doi:10.1021/jo001187f.
- ↑ Constantin Mamata, Martin Heina and Ralf Miethchen (2006). "Fluorinated acyclo-C-nucleoside analogues from glycals in two steps". Carbohydr. Res. 341 (10): 1758–1763. doi:10.1016/j.carres.2006.01.011. PMID 16442508.
See also
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