Eugenitin
From Self-sufficiency
Eugenitin | |
---|---|
Chemical structure of eugenitin | |
5-hydroxy-7-methoxy-2,6-dimethylchromen-4-one | |
style="background: #F8EABA; text-align: center;" colspan="2" | Identifiers | |
CAS number | 480-12-6 |
PubChem | 3083581 |
SMILES | Script error: No such module "collapsible list". |
style="background: #F8EABA; text-align: center;" colspan="2" | Properties | |
Molecular formula | C12H12O4 |
Molar mass | 220.22 g/mol |
Exact mass | 220.073559 u |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Infobox references |
Eugenitin is a furanochromone, a type of polyphenolic compound found in cloves. It has also been isolated from the fungal species Cylindrocarpon sp. C.M.I. 127996[1].
Synthesis
Eugenitin has also synthetised using the Kostanecki sodium acetate-acetic anhydride cyclization of C-methylphloracetophenone in 1952[2] and from visnagin, khellin and khellol in 1953[3].
See also
References
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- ↑ Fungal metabolites. I. Chromone and naphthoquinone metabolites from a Cylindrocarpon species. RG Coombe, HIC Lowe and TR Watson, Australian Journal of Chemistry 25(4) pp. 875-879, doi:10.1071/CH9720875
- ↑ A New Synthesis of Eugenitin. B. Whalley, J. Am. Chem. Soc., 1952, 74 (22), pp 5795–5796, DOI: 10.1021/ja01142a530
- ↑ Furo-chromones and -Coumarins. VII. Degradation of Visnagin, Khellin and Related Substances; Experiments with Chromic Acid and Hydrogen Peroxide; and a Synthesis of Eugenitin. Alexander Schönberg, Nasry Badran, Nicolas A. Starkowsky, J. Am. Chem. Soc., 1953, 75 (20), pp 4992–4995, DOI: 10.1021/ja01116a032