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  • .../ref><ref>{{Citation | last = Scoffern | first = John | title = The useful metals and their alloys | page = 6 | publisher = Houlston & Wright | year = 1869 | ...ndian Iron, Vikas Kumar and R. Balasubramaniam, ''International Journal of Metals, Materials and Processes'', Volume 14 (2002) pp. 1–14</ref> Furthermore,
    35 KB (5,392 words) - 10:22, 20 September 2010
  • ...state]]s. Iron and iron [[alloy]]s ([[steel]]s) are by far the most common metals and the most common [[ferromagnetic]] materials in everyday use. Fresh iron ...loying iron with appropriate small amounts (up to a few per cent) of other metals and carbon produces [[steel]], which can be 1,000&nbsp;times harder than pu
    67 KB (9,808 words) - 10:24, 20 September 2010
  • ...have been used as [[N-heterocyclic carbene]] ligands on various transition metals. It is found in the commercially available second generation [[Grubbs' cata
    2 KB (260 words) - 13:15, 20 September 2010
  • ...discovered the ability of ethylene oxide to react with acids and salts of metals.<ref name="oe1">{{cite book When carrying the thermal decomposition of ethylene oxide in the presence of transition metal compounds as catalysts, it is possible not only to reduce its tempera
    82 KB (11,709 words) - 21:31, 20 September 2010
  • ...]]s. The [[permanganate]]s of [[alkali metal|alkali]] and [[alkaline earth metals]] are powerful oxidizers. Manganese dioxide is used as the cathode (electro ...to give the atom a change in spin of two units. The unlikeliness of such a transition is seen in the uniformly pale and almost colorless nature of Mn(II) compoun
    44 KB (6,128 words) - 21:32, 20 September 2010
  • ...oatings: coatings for protection from oxidation of superalloys, refractory metals, and graphite|author = National Research Council (U.S.). Committee on Coati Chromium is a member of the [[transition metal]]s, in [[Group 6 element|group 6]]. Chromium(0) has an electronic con
    51 KB (7,299 words) - 21:34, 20 September 2010
  • ...hemistry'', 6th Edition, John Wiley and Sons (1999) Chapter 16: Survey of Transition-Metal Chemistry p. 633 ISBN 0471199575</ref> Average concentration in the e ...r [[laser]]. The highly [[monochromatic]] color arises from the 441.563 nm transition [[spectral line|line]] of cadmium.]]
    34 KB (4,743 words) - 21:34, 20 September 2010
  • ...]) seam. Materials recovered by mining include [[base metals]], [[precious metals]], [[iron]], [[uranium]], [[coal]], [[diamond]]s, [[limestone]], [[oil shal ...ious metals were also used mainly for gilding or coinage. Initially, many metals were obtained through [[open-pit mining]], and ore was primarily extracted
    50 KB (7,414 words) - 21:36, 20 September 2010
  • ...ing the ligands to alter the type of [[molecular encapsulation]] needed to metals; ...ands (and sometimes their bidentate versions Bm) are such that with late [[transition metal]]s such as osmium and [[platinum]] it is possible to turn the Tm liga
    9 KB (1,297 words) - 20:14, 21 September 2010
  • ...349-383. {{DOI|10.1021/cr020604g}}</ref> Terpy forms complexes with most [[transition metal]] [[ion]] as do other [[polypyridine complex|polypyridine compounds]] Because they are pi-acceptors, terpy and [[bipyridine]] too stabilize metals in lower oxidation states. For instance in [[acetonitrile]] solution, it is
    4 KB (504 words) - 20:14, 21 September 2010
  • Corrole normally serves as a [[anion|trianionic]] [[ligand]] with [[transition metal]]s.
    1 KB (143 words) - 20:14, 21 September 2010
  • ...entate]] [[Chelation|chelating]] [[ligand]], forming complexes with many [[transition metal]]s. [[Ruthenium]] complex and [[platinum]] complexes of bipy exhibit These and other [[homoleptic]] tris-2,2'-bipy complexes of many transition [[metals]] are electroactive. Often, both the [[metal]] centred and ligand centred
    5 KB (638 words) - 20:14, 21 September 2010
  • ...metric and binds to one face of an octahedron of metalloids and transition metals. The (TACN)M unit is kinetically inert, allowing further synthetic transfor *Although TACN characteristically coordinates to metals in mid- and high oxidation states, e.g. Ni(III), Mn(IV), Mo(III), W(III),
    5 KB (765 words) - 20:14, 21 September 2010
  • ...ry amines and carbon disulfide. They are used as [[chelating agents]] for transition metal ions and as precursors to [[herbicide]]s and [[vulcanization]] reagen The diethyldithiocarbamate ion chelates to many "[[HSAB theory|softer]]" metals via the two sulfur atoms. Other more complicated bonding modes are known i
    5 KB (586 words) - 20:15, 21 September 2010
  • ...In contrast, [[EDTA]] possesses 6 centres to form coordination bonds with metals.<ref>Each nitrogen centre counts as a centre of coordination, as does each ...]], DTPA wraps around a metal ion by forming up to eight bonds. Transition metals, however, usually have a limited coordination capacity and can form less th
    6 KB (825 words) - 20:15, 21 September 2010
  • The acetylacetonate [[anion]] forms complexes with many [[transition metal]] ions wherein both oxygen atoms bind to the metal to form a six-memb ...carbon atom; this bonding mode is more common for the third-row transition metals such as platinum(II) and iridium(III).
    16 KB (2,268 words) - 20:15, 21 September 2010
  • Triphos forms complexes with many [[transition metal]]s. It usually functions as a tripodal ligand that occupies three fac
    4 KB (589 words) - 20:15, 21 September 2010
  • ...[[peroxide]] bleaching to prevent degradation of peroxides by [[transition metals]].
    4 KB (491 words) - 20:15, 21 September 2010
  • ...compounds via [[ion exchange]]. It is noteworthy for its ability to bind [[transition metal]] ions. A concentrated solution of metals is obtained by eluting the resin with a small volume of 2 [[molarity|M]] [[
    1 KB (161 words) - 20:16, 21 September 2010
  • ...[[Coordination complex|complexes]] of the [[divalent]] ions of first-row [[transition metal]]s, the [[Stability constants of complexes|stability constant]] for t ...H. M. N. H.| coauthors=Williams, R. J. P.|date=1953|title=The stability of transition-metal complexes|journal=[[Journal of the Chemical Society|J. Chem. Soc.]]|p
    4 KB (545 words) - 20:16, 21 September 2010

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