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- Chromium, unlike metals such as iron and nickel, does not suffer from [[hydrogen embrittlement]]. However, it does suffer from nitrogen embrittlement, react Chromium(VI) compounds in solution can be detected by adding an acidic [[hydrogen peroxide]] solution. The unstable dark blue [[chromium(VI) peroxide]] (CrO<51 KB (7,299 words) - 21:34, 20 September 2010
- ...hyde is a naturally occurring substance in the environment made of carbon, hydrogen and oxygen. Natural processes in the upper [[Earth's atmosphere|atmosphere] When combined with hydrogen sulfide it forms [[trithiane]].<ref>{{OrgSynth | last1 = Bost | first1 = R.34 KB (4,726 words) - 21:35, 20 September 2010
- ...of four [[pyrrole]] rings joined together by four methine (=[[Carbon|C]][[Hydrogen|H]]—) [[functional group|group]]s to form a larger [[macrocycle]] rin ...m]]s, all of which are part of a [[Conjugated system|conjugated]] [[double bond]] system, giving the [[molecule]] its aromatic character. [[Resonance stru3 KB (467 words) - 20:14, 21 September 2010
- Catechol is produced industrially by the hydroxylation of [[phenol]] using [[hydrogen peroxide]]:<ref name=Ullmann>Helmut Fiegel, Heinz-Werner Voges, Toshikazu H ...derivative, [[guaiacol]], converts to catechol via hydrolysis of the CH3-O bond as promoted by [[hydriodic acid]].{{Fact|date=October 2007}}11 KB (1,437 words) - 20:14, 21 September 2010
- | title = Mechanism of Phosphorus-Carbon Bond Cleavage by Lithium in Tertiary Phosphines. An Optimized Synthesis of 1, 2- Treatment of dppe with conventional oxidants such as [[hydrogen peroxide]] (H<sub>2</sub>O<sub>2</sub>), aqueous [[bromine]] (Br<sub>2</sub5 KB (722 words) - 20:14, 21 September 2010
- ...limited coordination capacity and can form less than eight [[coordination bond]]s with [[ligand]]s. So, after forming a complex with a metal, DTPA still h ..., DTPA is mainly used for sequestering metal ions that otherwise decompose hydrogen peroxide, which is used to bleach pulp in paper making. Several million ki6 KB (825 words) - 20:15, 21 September 2010
- ...high in nonpolar solvents; the keto form becomes more favorable in polar, hydrogen-bonding solvents, such as water.<ref>''Solvents and Solvent Effects in Orga ...ons, D.W. and Steiner, W. "Acetylacetone-Cleaving Enzyme Dke1: A Novel C-C-Bond-Cleaving Enzyme." Biochem. J. 369 (2003) 573-581 {{DOI|10.1042/BJ20021047}}16 KB (2,268 words) - 20:15, 21 September 2010
- ...p> adopt more complex structures due to (i) the formation of an additional bond to water, i.e. seven-coordinate complexes, or (ii) the displacement of one ...specially Mn<sup>2+</sup>, from catalyzing the [[disproportionation]] of [[hydrogen peroxide]], which is used in "chlorine-free bleaching." In similar manner,21 KB (3,011 words) - 16:51, 27 September 2010
- ...camethylferrocene attached mechanically to a graphite electrode | author = Bond AM, Marken F | title = Mechanistic aspects of the electron and ion transpor ...get reasonable correlations, the most common elements contained in drugs (hydrogen, carbon, oxygen, sulfur, nitrogen, and halogens) are divided into several d27 KB (3,780 words) - 20:16, 21 September 2010
- ...molecules of [[water (molecule)|water]] (H<sub>2</sub>O) are split into [[hydrogen]] [[cation]]s (H<sup>+</sup>) (conventionally referred to as [[proton]]s) a ...mpounds). It should not be confused with [[hydrogenolysis]], a reaction of hydrogen.14 KB (2,113 words) - 20:16, 21 September 2010
- ...petition for the ligand, L, between the metal ion, M<sup>n+</sup>, and the hydrogen ion, H<sup>+</sup>. This means that there are two simultaneous equilibria t Hence by following the hydrogen ion concentration during a [[titration]] of a mixture of M and HL with [[Ba50 KB (7,450 words) - 20:16, 21 September 2010
- ...intermolecular interactions]] between the two molecules such as [[hydrogen bond]]ing, [[electrostatic| electrostatic interactions]], [[hydrophobic]] and [[10 KB (1,434 words) - 20:16, 21 September 2010
- ...cetate]] ion and the [[hydronium]] ion. Red: oxygen, black: carbon, white: hydrogen.]] ...to A<sup>−</sup>, known as the [[conjugate base]] of the acid, and the [[hydrogen ion]] or [[proton]], H<sup>+</sup>, which, in the case of aqueous solutions76 KB (11,861 words) - 20:17, 21 September 2010
- ...ulfide|H<sub>2</sub>S]], [[hydrogen telluride|H<sub>2</sub>Te]], and the [[hydrogen halide|hydrohalic acids]]. However, Davy failed to develop a new theory, co === Liebig's hydrogen theory of acids ===29 KB (4,415 words) - 20:17, 21 September 2010
- ::[H<sub>3</sub>O<sup>+</sup>] = molarity of hydrogen or hydronium ion, and ...ter molecules by the [[Grotthuss mechanism]]; and a change in the hydrogen bond network in the solvent isolates the two ions, which are stabilized by solva9 KB (1,347 words) - 20:17, 21 September 2010
- This law is strictly valid only under the assumption that the [[chemical bond|chemical interactions]] ''between'' the two liquids is equal to the bonding ...chloroform and acetone show such an attraction by formation of a hydrogen bond.11 KB (1,748 words) - 20:17, 21 September 2010
- ...ut in water, a [[covalent]] bond between an [[electronegative]] atom and a hydrogen atom is broken by [[heterolytic fission]], which gives a proton and a negat7 KB (979 words) - 20:17, 21 September 2010
- ...ase (chemistry)|base]] is a species with the ability to gain or "accept" a hydrogen cation (proton). ...or nitrogen atom with a lone pair of electrons that can be used to form a bond with a proton.6 KB (987 words) - 20:17, 21 September 2010
- ...s [[nitrogenase]]. Much energy is needed initially to break the N-N triple bond even though the overall reaction is exothermic. ...ecies of citric acid as a function of p H. Citric acid has three ionisable hydrogen atoms and thus three p K A values. Below the lowest p K A, the triply proto42 KB (6,675 words) - 20:17, 21 September 2010
- ...in hemoglobin form alpha helices, connected by short non-helical segments. Hydrogen bonds stabilize the helical sections inside this protein, causing attractio ...ng. A sixth position can reversibly bind oxygen by a [[coordinate covalent bond]],<ref>[http://wikipremed.com/interdisciplinary_course.php?code=0213000100067 KB (9,844 words) - 20:17, 21 September 2010
- ...e stabilization of the [[conjugate base]] by its formation of a [[hydrogen bond]] to the parent acid. A well known case is [[hydrofluoric acid]], which is2 KB (258 words) - 20:17, 21 September 2010
- ...reactive because nitrogen molecules are held together by strong [[Chemical bond|triple bonds]]. It was not until the early 20th century that this method wa ...cess, which is only concerned with synthesizing ammonia from nitrogen and hydrogen.16 KB (2,339 words) - 20:17, 21 September 2010
- | title = Molecular hydrogen complexes: coordination of a σ bond to transition metals | title = Metal Dihydrogen and σ-Bond Complexes - Structure, Theory, and Reactivity11 KB (1,575 words) - 20:18, 21 September 2010
- ...n. This process proceeds with retention of configuration about the double bond. ...]]. Reductive elimination is the key product releasing step of several C-C bond formation coupling reactions.<ref>Organometallics, 2005, 24, 715. {{DOI|10.3 KB (457 words) - 20:18, 21 September 2010
- ...activation process for complexes that often limits their ability for [[C-H bond activation]]. The organic substituents also define a hydrophobic pocket ar ...ynes]]<sup>6</sup>, [[alkane dehydrogenation]]<sup>7,8</sup>, and transfer hydrogen [[catalysis]].<sup>9</sup> They have also recently been studied for their u5 KB (747 words) - 20:18, 21 September 2010
- ...es where the ligands in the first coordination ligands are strong hydrogen-bond donors and acceptors, e.g. respectively [Co(NH<sub>3</sub>)<sub>6</sub>]<su3 KB (492 words) - 20:18, 21 September 2010
- ...ies of the complex. '''[[X-ray crystallography]]''' is used to measure the bond distances between the metal and the ligands, which give insight into the sp Due to the change in the metal-to-ligand bond distance (M-L) between the HS and LS state, the vibrational modes of the M-29 KB (4,717 words) - 20:18, 21 September 2010
- ...ally-occurring [[carboxylic acid]] with [[chemical formula]] [[carbon|C]][[hydrogen|H]]<sub>3</sub>CH<sub>2</sub>C[[oxygen|O]]OH. It is a clear liquid with a ...y adding salt. As with acetic and formic acids, it consists of [[hydrogen bond]]ed pairs of molecules both as the liquid and vapor.10 KB (1,395 words) - 22:06, 21 September 2010
- ...] linked to each other to form a ring, with each carbon atom bearing two [[hydrogen]] atoms. Cyclopropane and [[propene]] have the same [[empirical formula]] b ...on of methylene [[carbene]]s {{Citation needed|date=January 2009}}. [[Bent bond]]s also describe the bonding in cyclopropane.16 KB (2,099 words) - 21:00, 24 September 2010
- ...from its oil-forming property). Because it contains a carbon-carbon double bond, ethylene is classified as an ''unsaturated hydrocarbon.'' Ethylene is wide ...about the C-C bond is a high energy process that requires breaking the π-bond.32 KB (4,462 words) - 21:01, 24 September 2010
- ...em of the low terrestrial xenon may potentially be explained by [[covalent bond]]ing of xenon to oxygen within [[quartz]], hence reducing the outgassing of ...ure process ([[s-process]]) of [[red giant]] stars that have exhausted the hydrogen at their cores and entered the [[asymptotic giant branch]],<ref>{{cite jour82 KB (11,842 words) - 21:02, 24 September 2010
- ...s the [[organic compound]] with [[chemical formula|formula]] [[Carbon|C]][[Hydrogen|H]][[Chlorine|Cl]]<sub>3</sub>. The colorless, sweet-smelling, dense liquid ...G|last5=Snoeijs|first5=P|title=Effects of temperature on the production of hydrogen peroxide and volatile halocarbons by brackish-water algae.|volume=64|issue=21 KB (2,827 words) - 21:03, 24 September 2010
- ...bonds with the two carbon atoms. The elimination of double-bonds by adding hydrogen atoms is called ''[[saturated fat|saturation]]''; as the degree of [[satura ..., each carbon forming a new single-bond with a hydrogen atom. Adding these hydrogen atoms to the oil makes it more solid, raises the [[smoke point]], and makes32 KB (4,810 words) - 19:39, 13 October 2010