Non-Newtonian fluid
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A non-Newtonian fluid is a fluid whose flow properties are not described by a single constant value of viscosity. Many polymer solutions and molten polymers are non-Newtonian fluids, as are many commonly found substances such as ketchup, starch suspensions, paint, blood and shampoo. In a Newtonian fluid, the relation between the shear stress and the strain rate is linear, passing through the origin, the constant of proportionality being the coefficient of viscosity. In a non-Newtonian fluid, the relation between the shear stress and the strain rate is nonlinear, and can even be time-dependent. Therefore a constant coefficient of viscosity cannot be defined.
Although the concept of viscosity is commonly used to characterize a material, it can be inadequate to describe the mechanical behavior of a substance, particularly non-Newtonian fluids. They are best studied through several other rheological properties which relate the relations between the stress and strain rate tensors under many different flow conditions, such as oscillatory shear, or extensional flow which are measured using different devices or rheometers. The properties are better studied using tensor-valued constitutive equations, which are common in the field of continuum mechanics.
Contents
Types of non-Newtonian behavior
Summary
Viscoelastic | Kelvin material | "Parallel" linear combination of elastic and viscous effects | |
Anelastic | Material returns to a well-defined "rest shape" | ||
Time-dependent viscosity | Rheopectic | Apparent viscosity increases with duration of stress[1] | Some lubricants, whipped cream |
Thixotropic | Apparent viscosity decreases with duration of stress[2] | Some Clays, Some Drilling Mud, many paints, synovial fluid, Honey under certain conditions | |
Time-independent viscosity | Shear thickening (dilatant) | Apparent viscosity increases with increased stress[3] | Suspensions of corn starch or sand in water |
Shear thinning (pseudoplastic) | Apparent viscosity decreases with increased stress[4][5] | Paper pulp in water, latex paint, ice, blood, syrup, molasses | |
Generalized Newtonian fluids | Viscosity is constant Stress depends on normal and shear strain rates and also the pressure applied on it |
Blood plasma, Custard |
Shear thickening fluids
Shear thickening fluids are also used in all wheel drive systems utilising a viscous coupling unit for power transmission.
Shear thinning fluid
A familiar example of the opposite, a shear thinning fluid, or pseudoplastic fluid, is paint: one wants the paint to flow readily off the brush when it is being applied to the surface being painted, but not to drip excessively.
Bingham plastic
There are fluids which have a linear shear stress/shear strain relationship which require a finite yield stress before they begin to flow (the plot of shear stress against shear strain does not pass through the origin). These fluids are called Bingham plastics. Several examples are clay suspensions, drilling mud, toothpaste, mayonnaise, chocolate, and mustard.
Rheopectic
There are also fluids whose strain rate is a function of time. Fluids that require a gradually increasing shear stress to maintain a constant strain rate are referred to as rheopectic. An opposite case of this, is a fluid that thins out with time and requires a decreasing stress to maintain a constant strain rate (thixotropic).
Examples
Oobleck
An inexpensive, non-toxic example of a non-Newtonian fluid is a suspension of starch (e.g. cornflour) in water, sometimes called "oobleck" or "ooze" (2 parts corn starch to 1 part water).[7][8] Uncooked imitation custard, being a suspension of primarily cornflour, has the same properties. The name "oobleck" is derived from the children's book Bartholomew and the Oobleck. A person moving quickly and applying sufficient force with their feet can literally walk across such a liquid.[9]
Glurch
A substance known as "glurch"—a mixture of a borax solution and white glue, and optionally salt—is also commonly used to demonstrate non-Newtonian fluids.[10]
Chilled caramel topping
Another example of this is chilled caramel ice cream topping. The sudden application of force—for example by stabbing the surface with a finger, or rapidly inverting the container holding it—leads to the fluid behaving like a solid rather than a liquid. This is the "shear thickening" property of this non-Newtonian fluid. More gentle treatment, such as slowly inserting a spoon, will leave it in its liquid state. Trying to jerk the spoon back out again, however, will trigger the return of the temporary solid state.
Silly Putty
Silly Putty, is a silicone polymer based suspension which will flow, bounce, or break depending on strain rate.
Ketchup
Ketchup is a thixotropic fluid.[3] Thixotropy means that the fluid viscosity is inversely proportional to the shear rate. In other words, fluid motion is initially difficult to start, but once flowing will continue to do so freely.
See also
- Bingham plastic
- Complex fluid
- Dissipative particle dynamics
- Newtonian fluid
- Herschel–Bulkley fluid
- Navier–Stokes equations
- Pseudoplastic
- Dilatant
- Quicksand
- Rheology
- Superfluids
References
- ↑ Springer handbook of experimental fluid mechanics, Cameron Tropea, Alexander L. Yarin, John F. Foss, Publisher: Springer, 9 Oct 2007, ISBN-10: 3540251413, ISBN-13: 978-3540251415, p.676, Google books
- ↑ Springer handbook of experimental fluid mechanics, Cameron Tropea, Alexander L. Yarin, John F. Foss, Publisher: Springer, 9 Oct 2007, ISBN-10: 3540251413, ISBN-13: 978-3540251415, p.661, Google books
- ↑ 3.0 3.1 Pump Application Desk Book, 3rd edition, Paul N. Garay, Prentice Hall, August 1996, ISBN-10: 0881732311, ISBN-13: 978-0881732313, p.358, Google books
- ↑ Rheology of Fluid and Semisolid Foods: Principles and Applications, M. A. Rao, Publisher: Springer, 2nd edition, 28 Aug 2007, ISBN-10: 0387709290, ISBN-13: 978-0387709291, p.8, Google books
- ↑ Emulsions, Foams, and Suspensions: Fundamentals and Applications, Laurier L. Schramm, Publisher: Wiley VCH, 26 July 2005, ISBN-10: 3527307435, ISBN-13: 978-3527307432p.173, Google books
- ↑ This demonstration of oobleck is a popular subject for YouTube videos, such as this.
- ↑ Oobleck: The Dr. Seuss Science Experiment
- ↑ Outrageous Ooze
- ↑ YouTube Video of Mythbusters- Walking on "Water"
- ↑ Glurch Meets Oobleck. Iowa State University Extension.
External links
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