# Stainless steel

Iron alloy phases

Ferrite (α-iron, δ-iron)
Austenite (γ-iron)
Pearlite (88% ferrite, 12% cementite)
Martensite
Bainite
Ledeburite (ferrite-cementite eutectic, 4.3% carbon)
Cementite (iron carbide, Fe3C)

Steel classes

Crucible steel
Carbon steel (≤2.1% carbon; low alloy)

Spring steel (low or no alloy)

Alloy steel (contains non-carbon elements)

Maraging steel (contains nickel)
Stainless steel (contains ≥10.5% chromium)
Weathering steel
Tool steel (alloy steel for tools)
Other iron-based materials

Cast iron (>2.1% carbon)

Ductile iron
Gray iron
Malleable iron
White iron

Wrought iron (contains slag)

File:Gateway arch.jpg
The 630-foot (192 m) high, stainless-clad (type 304) Gateway Arch defines St. Louis's skyline.

In metallurgy stainless steel, also known as inox steel or inox from French "inoxydable", is defined as a steel alloy with a minimum of 10.5[1] or 11% chromium content by mass.[2] Stainless steel does not stain, corrode, or rust as easily as ordinary steel, but it is not stain-proof.[3] It is also called corrosion-resistant steel or CRES when the alloy type and grade are not detailed, particularly in the aviation industry. There are different grades and surface finishes of stainless steel to suit the environment to which the material will be subjected in its lifetime. Stainless steel is used where both the properties of steel and resistance to corrosion are required.

Stainless steel differs from carbon steel by the amount of chromium present. Carbon steel rusts when exposed to air and moisture. This iron oxide film (the rust) is active and accelerates corrosion by forming more iron oxide. Stainless steels contain sufficient chromium to form a passive film of chromium oxide, which prevents further surface corrosion and blocks corrosion from spreading into the metal's internal structure.

## History

File:Stainless steel nyt 1-31-1915.jpg
An announcement, as it appeared in the 1915 New York Times, of the development of stainless steel.[4]

A few corrosion-resistant iron artifacts survive from antiquity. A famous (and very large) example is the Iron Pillar of Delhi, erected by order of Kumara Gupta I around the year AD 400. Unlike stainless steel, however, these artifacts owe their durability not to chromium, but to their high phosphorus content, which, together with favorable local weather conditions, promotes the formation of a solid protective passivation layer of iron oxides and phosphates, rather than the non-protective, cracked rust layer that develops on most ironwork.

The corrosion-resistance of iron-chromium alloys was first recognized in 1821 by the French metallurgist Pierre Berthier, who noted their resistance against attack by some acids and suggested their use in cutlery. Metallurgists of the 19th century, however, were unable to produce the combination of low carbon and high chromium found in most modern stainless steels, and the high-chromium alloys they could produce were too brittle to be practical.

In the late 1890s Hans Goldschmidt of Germany developed an aluminothermic (thermite) process for producing carbon-free chromium. Between 1904 and 1911 several researchers, particularly Leon Guillet of France, prepared alloys that would today be considered stainless steel.

Friedrich Krupp Germaniawerft built the 366-ton sailing yacht Germania featuring a chrome-nickel steel hull in Germany in 1908.[5] In 1911, Philip Monnartz reported on the relationship between chromium content and corrosion resistance. On October 17, 1912 Krupp engineers Benno Strauss and Eduard Maurer patented austenitic stainless steel.[6]

Similar developments were taking place contemporaneously in the United States, where Christian Dantsizen and Frederick Becket were industrializing ferritic stainless steel. In 1912, Elwood Haynes applied for U.S. patent on a martensitic stainless steel alloy, which was not granted until 1919.[7]

Also in 1912, Harry Brearley of the Brown-Firth research laboratory in Sheffield, England, while seeking a corrosion-resistant alloy for gun barrels, discovered and subsequently industrialized a martensitic stainless steel alloy. The discovery was announced two years later in a January 1915 newspaper article in The New York Times.[4] Brearley applied for a U.S. patent during 1915 only to find that Haynes had already registered a patent. Brearley and Haynes pooled their finding, and with a group of investors formed the American Stainless Steel Corporation, with headquarters in Pittsburgh, Pennsylvania. The metal was later marketed under the "Staybrite" brand by Firth Vickers in England and was used for the new entrance canopy for the Savoy Hotel in London in 1929.[8]

## Properties

High oxidation-resistance in air at ambient temperature is normally achieved with additions of a minimum of 13% (by weight) chromium, and up to 26% is used for harsh environments.[9] The chromium forms a passivation layer of chromium(III) oxide (Cr2O3) when exposed to oxygen. The layer is too thin to be visible, and the metal remains lustrous. The layer is impervious to water and air, protecting the metal beneath. Also, this layer quickly reforms when the surface is scratched. This phenomenon is called passivation and is seen in other metals, such as aluminium and titanium. Corrosion-resistance can be adversely affected if the component is used in a non-oxygenated environment, a typical example being underwater keel bolts buried in timber.

When stainless steel parts such as nuts and bolts are forced together, the oxide layer can be scraped off, causing the parts to weld together. When disassembled, the welded material may be torn and pitted, an effect known as galling. This destructive galling can be best avoided by the use of dissimilar materials for the parts forced together, e.g. bronze and stainless steel, or even different types of stainless steels (martensitic against austenitic, etc.), when metal-to-metal wear is a concern. Nitronic alloys (trademark of Armco, Inc.) reduce the tendency to gall through selective alloying with manganese and nitrogen. Threaded joints may also be lubricated to prevent galling.

## Applications

 File:Chrysler Building detail.jpg The pinnacle of New York's Chrysler Building is clad with type 302 stainless steel.[10] File:MohawkNiagraFacadeSculpture.jpg An art deco sculpture on the Niagara-Mohawk Power building in Syracuse, New York.

Stainless steel’s resistance to corrosion and staining, low maintenance, relatively low cost, and familiar luster make it an ideal base material for a host of commercial applications. There are over 150 grades of stainless steel, of which fifteen are most commonly used. The alloy is milled into coils, sheets, plates, bars, wire, and tubing to be used in cookware, cutlery, hardware, surgical instruments, major appliances, industrial equipment e.g. in sugar refineries, and as an automotive and aerospace structural alloy and construction material in large buildings. Storage tanks and tankers used to transport orange juice and other food are often made of stainless steel, due to its corrosion resistance and antibacterial properties. This also influences its use in commercial kitchens and food processing plants, as it can be steam-cleaned, sterilized, and does not need painting or application of other surface finishes.

Stainless steel is used for jewellery and watches. 316L is the stainless steel commonly used for such purpose. It can be re-finished by any jeweller and will not oxidize or turn black.

Some firearms incorporate stainless steel components as an alternative to blued or parkerized steel. Some handgun models, such as the Smith & Wesson Model 60 and the Colt M1911 pistol, can be made entirely from stainless steel. This gives a high-luster finish similar in appearance to nickel plating; but, unlike plating, the finish is not subject to flaking, peeling, wear-off due to rubbing (as when repeatedly removed from a holster over the course of time), or rust when scratched.

Some automotive manufacturers use stainless steel as decorative highlights in their vehicles.

### Uses in sculpture, building facades and building structures

• Stainless steel was in vogue during the art deco period. The most famous example of this is the upper portion of the Chrysler Building (pictured). Some diners and fast-food restaurants use large ornamental panels, stainless fixtures and furniture. Owing to the durability of the material, many of these buildings retain their original appearance.
• The forging of stainless steel has given rise to a fresh approach to architectural blacksmithing in recent years.

## Recycling and reuse

Stainless steel is 100% recyclable. An average stainless steel object is composed of about 60% recycled material of which approximately 40% originates from end-of-life products and about 60% comes from manufacturing processes.[13]

In fact, there is a secondary market that basically recycles usable scrap for many stainless steel markets. The product is mostly coil, sheet and blanks. This material is purchased at a less-than-prime price and sold to commercial quality stampers and sheet metal houses. The material may have scratches, pits and dents but is made to the current specifications.

## Types of stainless steel

File:Piping01.JPG
Pipes and fittings made of stainless steel.
File:Stainless Steel chair with yellow plastic in Rio de Janeiro Sea.jpg
Stainless steel chair in use in Rio de Janeiro, Brazil. The austenitic AISI 304 is suitable for use in marine regions due to its high oxidation resistance.

There are different types of stainless steels: when nickel is added, for instance, the austenite structure of iron is stabilized. This crystal structure makes such steels virtually non-magnetic and less brittle at low temperatures. For greater hardness and strength, more carbon is added. When subjected to adequate heat treatment, these steels are used as razor blades, cutlery, tools, etc.

Significant quantities of manganese have been used in many stainless steel compositions. Manganese preserves an austenitic structure in the steel as does nickel, but at a lower cost.

Stainless steels are also classified by their crystalline structure:

• Austenitic, or 300 series, stainless steels make up over 70% of total stainless steel production. They contain a maximum of 0.15% carbon, a minimum of 16% chromium and sufficient nickel and/or manganese to retain an austenitic structure at all temperatures from the cryogenic region to the melting point of the alloy. A typical composition of 18% chromium and 10% nickel, commonly known as 18/10 stainless, is often used in flatware. 18/0 and 18/8 are also available. Superaustenitic stainless steels, such as alloy AL-6XN and 254SMO, exhibit great resistance to chloride pitting and crevice corrosion due to high molybdenum content (>6%) and nitrogen additions, and the higher nickel content ensures better resistance to stress-corrosion cracking versus the 300 series. The higher alloy content of superaustenitic steels makes them more expensive. Other steels can offer similar performance at lower cost and are preferred in certain applications.[citation needed]. Low-carbon versions, for example 316L or 304L, are used to avoid corrosion problem caused by welding. Grade 316LVM is preferred where biocompatibility is required (such as body implants and piercings).[14] The "L" means that the carbon content of the alloy is below 0.03%, which reduces the sensitization effect (precipitation of chromium carbides at grain boundaries) caused by the high temperatures involved in welding.
• Ferritic stainless steels generally have better engineering properties than austenitic grades, but have reduced corrosion resistance, due to the lower chromium and nickel content. They are also usually less expensive. They contain between 10.5% and 27% chromium and very little nickel, if any, but some types can contain lead. Most compositions include molybdenum; some, aluminium or titanium. Common ferritic grades include 18Cr-2Mo, 26Cr-1Mo, 29Cr-4Mo, and 29Cr-4Mo-2Ni. These alloys can be degraded by the presence of $\sigma$ chromium, an intermetallic phase which can precipitate upon welding.
• Martensitic stainless steels are not as corrosion-resistant as the other two classes but are extremely strong and tough, as well as highly machineable, and can be hardened by heat treatment. Martensitic stainless steel contains chromium (12-14%), molybdenum (0.2-1%), nickel (0-<2%), and carbon (about 0.1-1%) (giving it more hardness but making the material a bit more brittle). It is quenched and magnetic.
• Precipitation-hardening martensitic stainless steels have corrosion resistance comparable to austenitic varieties, but can be precipitation hardened to even higher strengths than the other martensitic grades. The most common, 17-4PH, uses about 17% chromium and 4% nickel. The Lockheed-Martin Joint Strike Fighter is the first aircraft to use a precipitation-hardenable stainless steel—Carpenter Custom 465—in its airframe.

• Duplex stainless steels have a mixed microstructure of austenite and ferrite, the aim usually being to produce a 50/50 mix, although in commercial alloys the ratio may be 40/60. Duplex steels have twice the strength compared to austenitic stainless steels and also improved resistance to localised corrosion, particularly pitting, crevice corrosion and stress corrosion cracking. They are characterised by high chromium (19–28%) and molybdenum (up to 5%) and lower nickel contents than austenitic stainless steels. Duplex grades are characterized into groups based on their alloy content and corrosion resistance. Lean duplex refers to grades such as UNS S32101 (LDX 2101), S32304, and S32003. The standard duplex is 22% chromium with S31803/S32205 known as 2205 being the most widely used. Super duplex refers to 25% chromium grades such as S32760 (ZERON 100), S32750 (2507), and S32550 (Ferralium). Hyper duplex refers to higher chromium grades such as S32906. The properties of duplex stainless steels are achieved with an overall lower alloy content than similar-performing super-austenitic grades, making their use cost-effective for many applications.

### Comparison of standardized steels

EN-standard

Steel no. k.h.s DIN

EN-standard

Steel name

440A S44002
1.4112 440B S44003
1.4125 440C S44004
440F S44020
1.4016 X6Cr17 430 S43000
1.4408 G-X 6 CrNiMo 18-10 316
1.4512 X6CrTi12 409 S40900
410 S41000
1.4310 X10CrNi18-8 301 S30100
1.4318 X2CrNiN18-7 301LN N/A
1.4307 X2CrNi18-9 304L S30403
1.4306 X2CrNi19-11 304L S30403
1.4311 X2CrNiN18-10 304LN S30453
1.4301 X5CrNi18-10 304 S30400
1.4948 X6CrNi18-11 304H S30409
1.4303 X5CrNi18-12 305 S30500
X5CrNi30-9 312
1.4541 X6CrNiTi18-10 321 S32100
1.4878 X12CrNiTi18-9 321H S32109
1.4404 X2CrNiMo17-12-2 316L S31603
1.4401 X5CrNiMo17-12-2 316 S31600
1.4406 X2CrNiMoN17-12-2 316LN S31653
1.4432 X2CrNiMo17-12-3 316L S31603
1.4435 X2CrNiMo18-14-3 316L S31603
1.4436 X3CrNiMo17-13-3 316 S31600
1.4571 X6CrNiMoTi17-12-2 316Ti S31635
1.4429 X2CrNiMoN17-13-3 316LN S31653
1.4438 X2CrNiMo18-15-4 317L S31703
1.4539 X1NiCrMoCu25-20-5 904L N08904
1.4547 X1CrNiMoCuN20-18-7 N/A S31254

### Stainless steel grades

There are a number of different systems for grading stainless and other steels. The article on US SAE steel grades details a large number of grades with their properties.

### Stainless steel in 3D printing

Some 3D printing providers have developed proprietary stainless steel sintering[15] blends for use in rapid prototyping. Currently available grades do not vary in properties significantly.[16]

## Stainless steel finishes

File:316L Stainless Steel Unpolished.jpg
316L stainless steel, with an unpolished, mill finish.

Standard mill finishes can be applied to flat rolled stainless steel directly by the rollers and by mechanical abrasives. Steel is first rolled to size and thickness and then annealed to change the properties of the final material. Any oxidation that forms on the surface (scale) is removed by pickling, and a passivation layer is created on the surface. A final finish can then be applied to achieve the desired aesthetic appearance.

• No. 0: Hot rolled, annealed, thicker plates
• No. 1: Hot rolled, annealed and passivated
• No. 2D: Cold rolled, annealed, pickled and passivated
• No. 2B: Same as above with additional pass-through highly polished rollers
• No. 2BA: Bright annealed (BA or 2R) same as above then bright annealed under oxygen-free atmospheric conditions
• No. 3: Coarse abrasive finish applied mechanically
• No. 4: Brushed finish
• No. 5: Satin finish
• No. 6: Matte finish
• No. 7: Reflective finish
• No. 8: Mirror finish
• No. 9: Bead blast finish
• No. 10: Heat colored finish-wide range of electropolished & heat colored surfaces

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