Tolidine

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2-Tolidine[1]
File:2-tolidine.svg
style="background: #F8EABA; text-align: center;" colspan="2" | Identifiers
CAS number 119-93-7
PubChem 8413
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style="background: #F8EABA; text-align: center;" colspan="2" | Properties
Molecular formula C14H16N2
Molar mass 212.29 g mol−1
Density 1.23 g/cm3
Melting point

129 °C, 402 K, 264 °F

Boiling point

300.5 °C, 574 K, 573 °F

Solubility in water 1.3 g/L
style="background: #F8EABA; text-align: center;" colspan="2" | Hazards
R-phrases R45 R22 R51/53
S-phrases S53 S45 S61
Flash point 244 °C
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Toludine is a group of isomeric organic compounds, the most prevalent of which is 2-tolidine (o-tolidine).

Chemistry

2-Tolidine is slighly soluble in water (1.3 g/L) and has a melting point of 129 °C. It readily forms salts with acids, such as the hydrochloride which is commercially available. 2-Tolidine can be produced by a benzidine rearrangement from a hydrazine derivative.[2]

Uses

2-Tolidine is a commercially important aromatic amines used mainly for dye production, but also for the production of certain elastomers. 2-Tolidine is an intermediate for the production of soluble azo dyes and insoluble pigments used particularly in the textile, leather and paper industries.

2-Tolidine also widely used as a reagent or indicator in analytical, clinical and forensic chemistry, such as in the analytical determination of gold.

Safety

2-Tolidine is toxic and possibly carcinogenic. It is listed as an IARC Group 2B carcinogen, meaning it is "possibly carcinogenic to humans".

References

  1. Record of ortho-Tolidin in the GESTIS Substance Database from the IFA
  2. Noller, Carl R.: Textbook of Organic Chemistry, Springer Verlag, 1960
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